Giant magnetic anisotropy of single cobalt atoms and nanoparticles

The isotropic magnetic moment of a free atom is shown to develop giant magnetic anisotropy energy due to symmetry reduction at an atomically ordered surface. Single cobalt atoms deposited onto platinum ( 111) are found to have a magnetic anisotropy energy of 9 millielectron volts per atom arising from the combination of unquenched orbital moments (1.1 Bohr magnetons) and strong spin-orbit coupling induced by the platinum substrate. By assembling cobalt nanoparticles containing up to 40 atoms, the magnetic anisotropy energy is further shown to be dependent on single-atom coordination changes. These results confirm theoretical predictions and are of fundamental value to understanding how magnetic anisotropy develops infinite-sized magnetic particles.


Published in:
Science, 300, 5622, 1130-1133
Year:
2003
ISSN:
0036-8075
ISBN:
0036-8075
Keywords:
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 Record created 2009-04-14, last modified 2018-03-17

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