An Iron Carbonyl Pyridonate Complex Related to the Active Site of the [Fe]-Hydrogenase (Hmd)
Obrist, Blaise V.; Chen, Dafa; Ahrens, Anne; Schünemann, Volker; Scopelliti, Rosario; Hu, Xile
2009

Abstract

A mononuclear iron bis(carbonyl) pyridonate complex (1), which exhibits several common structural features with the active site of the iron−sulfur cluster-free [Fe]- hydrogenase, was synthesized and characterized. Spectroscopic data of 1 suggests a 2+ oxidation state for the Fe ion in the [Fe]-hydrogenase. Complex 1 serves as a precursor to other hydrogenase models.

Details

Title An Iron Carbonyl Pyridonate Complex Related to the Active Site of the [Fe]-Hydrogenase (Hmd)
Author(s) Obrist, Blaise V. ; Chen, Dafa ; Ahrens, Anne ; Schünemann, Volker ; Scopelliti, Rosario ; Hu, Xile
Published in Inorganic Chemistry
Volume 48
Issue 8
Pages 3514-3516
Date 2009
Keywords
DOI https://doi.org/10.1021/ic900281g
Other identifier(s) View record in Web of Science
Laboratories LSCI
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LSCI - Laboratory of Inorganic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2009-03-20

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