000130402 001__ 130402
000130402 005__ 20180913055018.0
000130402 0247_ $$2doi$$a10.1016/j.tet.2008.11.007
000130402 02470 $$2ISI$$a000262797900010
000130402 037__ $$aARTICLE
000130402 245__ $$aPalladium-catalyzed desulfinylative C–C allylation of  Grignard reagents and enolates using allylsulfonyl  chlorides and esters
000130402 269__ $$a2009
000130402 260__ $$c2009
000130402 336__ $$aJournal Articles
000130402 520__ $$a2-Methylprop-2-ene-, prop-2-ene-, 1-methylprop-2-ene-, and  (E)-but-2-enesulfonyl chlorides have been used as  electrophilic partners in desulfinylative palladium- catalyzed C–C coupling with Grignard reagents and sodium  salts of dimethyl malonate and methyl acetoacetate.  Neopentyl alk-2-ene sulfonates can also be used as  electrophilic partners in desulfinylative allylic  arylations and allylic alkylations. The regioselectivity of  the allylic arylation and alkylation depends on the nature  of the catalyst. With PdCl2(PhCN)2, (E)-crotyl derivatives  are formed in high regioselectivity using either 1- methylprop-2-eneor (E)-but-2-enesulfonyl chloride.
000130402 6531_ $$aAllylic alkylation
000130402 6531_ $$aAllylic arylation
000130402 6531_ $$aHomogenous catalysis
000130402 6531_ $$aRegioselective allylation
000130402 6531_ $$aPalladium complexes
000130402 6531_ $$aSulfonate esters
000130402 6531_ $$aSulfonyl chlorides
000130402 6531_ $$aGrignard reagents
000130402 700__ $$aVolla, Chandra M Rao
000130402 700__ $$0241356$$aDubbaka, Srinivas Reddy$$g148846
000130402 700__ $$0240222$$aVogel, Pierre$$g123681
000130402 773__ $$j65$$k2$$q504$$tTetrahedron
000130402 8564_ $$zURL
000130402 8564_ $$s373799$$uhttps://infoscience.epfl.ch/record/130402/files/mouli%20palladium.pdf$$zn/a
000130402 909C0 $$0252076$$pLGSA$$xU10111
000130402 909CO $$ooai:infoscience.tind.io:130402$$pSB$$particle
000130402 937__ $$aLGSA-ARTICLE-2008-011
000130402 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000130402 980__ $$aARTICLE