000125797 001__ 125797
000125797 005__ 20180913054650.0
000125797 02470 $$2DAR$$a12852
000125797 02470 $$2ISI$$a000256239600010
000125797 0247_ $$2doi$$a10.1016/j.jinorgbio.2007.10.016
000125797 037__ $$aARTICLE
000125797 245__ $$aStudies on the reactivity of organometallic Ru-, Rh- and Os-pta complexes with DNA model compounds
000125797 269__ $$a2008
000125797 260__ $$c2008
000125797 336__ $$aJournal Articles
000125797 520__ $$aThe reactions of arene-metal complexes (arene = p-cymene, benzene or pentamethylcyclopentadienyl, metal = Ru, Rh or Os), including 1,3,5-triaza-7-phosphatricyclo-[3.3.1.1]decanephosphine (pta) and chloro co-ligands, with 9-methylguanine, adenine, and a series of nucleosides were studied in water to ascertain the binding modes.  The products were characterized by NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS).  Tandem mass spectrometry was found to provide excellent information on preferential binding sites.  In general, the N7 position on guanine (the most basic site) was the preferred donor atom for coordination to the metal complexes.  The x-ray structures of the precursor complexes, [(h5-C10H15)RhCl(pta-Me)2]Cl2, [(h6-C10H14)OsCl(pta)2]Cl, and [(h6-C6H6)OsCl2(CH3CN)], are also reported. 
000125797 700__ $$0240281$$aDorcier, Antoine$$g155779
000125797 700__ $$aHartinger, Christian G.
000125797 700__ $$0240189$$aScopelliti, Rosario$$g148592
000125797 700__ $$aFish, Richard H.
000125797 700__ $$aKeppler, Bernhard K.
000125797 700__ $$0240015$$aDyson, Paul J.$$g149418
000125797 773__ $$j102$$k5-6$$q1066-1076$$tJOURNAL OF INORGANIC BIOCHEMISTRY
000125797 909C0 $$0252010$$pLCOM$$xU9
000125797 909CO $$ooai:infoscience.tind.io:125797$$pSB$$particle
000125797 937__ $$aLCOM-ARTICLE-2008-057
000125797 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000125797 980__ $$aARTICLE