Journal article

Synthesis and Characterization of N-Heterocyclic Carbene Complexes of Uranium(III)

Reaction of [((AdArO)3tacn)UIII] (1) or [((Me3Si)2N)3UIII] (3) with tetramethylimidazol-2-ylidene (Me4IMC:) yields novel N-heterocyclic carbene complexes [((AdArO)3tacn)UIII(Me4IMC:)] (2) and [((Me3Si)2N)3UIII(Me4IMC:)] (4). Uranium complexes 2 and 4 represent the first examples of compds. with an N-heterocyclic carbene ligand coordinated to a low-valent uranium center. The paramagnetic complexes 1, 2, and 4 were characterized by 1H NMR, UV-vis-NIR, and EPR spectroscopy as well as SQUID magnetization measurements and x-ray diffraction analyses. DFT studies indicate a significant degree of pi-bonding in the U(III)-carbene entity. [on SciFinder (R)]


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