Identification of iron cyclam complexes encapsulated inside zeolite Y
Hu, Xile; Meyer, Karsten
2002

Abstract

The combination of EPR and Mossbauer spectroscopy along with IR, Diffuse Reflectance UV-visible, and XRD techniques proved to be a powerful tool for identifying and characterizing the mol. and electronic structure of various Fe complexes formed inside the supercages of zeolite-Y. Esp. interesting is the identification of encapsulated trans-[(cyclam)Fe(N3)2]+@NaY, as a potent precursor for the synthesis of catalytically active Fe(V) nitrido species. [on SciFinder (R)]

Details

Title Identification of iron cyclam complexes encapsulated inside zeolite Y
Author(s) Hu, Xile ; Meyer, Karsten
Published in Inorganica Chimica Acta
Volume 337
Pages 53-58
Date 2002
Keywords
Reflection spectra (UV-visible diffuse; identification of; iron cyclam complexes encapsulated inside zeolite Y using); UV and visible spectra (diffuse reflection; identification; of iron cyclam complexes encapsulated inside zeolite Y; using); Y zeolites Role: PEP (Physical; engineering or chemical process); PYP (Physical process); PROC (Process) (identification of iron cyclam complexes; encapsulated inside zeolite Y); ESR; IR spectra; Mossbauer; effect; X-ray diffraction (identification of iron cyclam; complexes encapsulated inside zeolite Y using); Electronic; structure (identification of iron cyclam complexes; encapsulated inside zeolite Y with); iron complex cyclam encapsulation zeolite Y optical spectra; Mossbauer spectra iron complex cyclam encapsulation zeolite; Y; electronic structure iron complex cyclam encapsulation; zeolite Y; IR spectra iron complex cyclam encapsulation; zeolite Y; x ray diffraction iron complex cyclam; encapsulation zeolite Y; UV visible diffuse reflection iron; complex cyclam zeolite Y
Note CAN 138:80084 73-4 Optical, Electron, and Mass Spectroscopy and Other Related Properties Department of Chemistry and Biochemistry,University of California, San Diego,La Jolla,CA,USA. Journal 0020-1693 written in English. 7439-89-6 (Iron); 20074-52-6 (Iron 3+) Role: PRP (Properties) (identification of iron cyclam complexes encapsulated inside zeolite Y); 481646-04-2P; 481667-80-5P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (identification of iron cyclam complexes encapsulated inside zeolite Y); 295-37-4 (Cyclam); 4648-54-8 (Trimethylsilyl azide); 7705-08-0 (Iron trichloride) Role: RCT (Reactant), RACT (Reactant or reagent) (iron cyclam complexes encapsulated inside zeolite Y using)
DOI https://doi.org/10.1016/S0020-1693(02)01079-4
Laboratories LSCI
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LSCI - Laboratory of Inorganic Synthesis and Catalysis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2007-12-17

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