Alkene hydrazination: Catalytic hydrohydrazination of a wide range of alkenes with a simple Mn complex
2004
Abstract
Enhanced activity, lower catalyst loading, shorter reaction time, and expanded substrate scope are the advantages of [Mn(dpm)3] over Co catalysts in the hydrohydrazination reaction of alkenes. Thus, sterically hindered alkenes, including tetrasubstituted alkenes, can now also readily undergo this reaction. [on SciFinder (R)]
Details
Title
Alkene hydrazination: Catalytic hydrohydrazination of a wide range of alkenes with a simple Mn complex
Author(s)
Waser, Jerome ; Carreira, Erick M.
Published in
Angewandte Chemie, International Edition
Volume
43
Issue
31
Pages
4099-4102
Date
2004
ISSN
1433-7851
Keywords
Note
CAN 141:331638
21-2
General Organic Chemistry
Laboratorium fuer Organische Chemie,ETH Honggerberg,Zurich,Switz.
Journal
written in English.
704900-51-6P Role: CAT (Catalyst use), SPN (Synthetic preparation), PREP (Preparation), USES (Uses) (cobalt- or manganese-catalyzed hydrohydrazination of alkenes); 62-57-7 (2-Aminoisobutyric acid); 90-02-8 (Salicylaldehyde) Role: RCT (Reactant), RACT (Reactant or reagent) (cobalt- or manganese-catalyzed hydrohydrazination of alkenes); 773882-01-2P Role: BYP (Byproduct), SPN (Synthetic preparation), PREP (Preparation) (manganese-catalyzed hydrohydrazination of alkenes); 14324-99-3P Role: CAT (Catalyst use), SPN (Synthetic preparation), PREP (Preparation), USES (Uses) (manganese-catalyzed hydrohydrazination of alkenes); 67-64-1 (Acetone); 91-20-3 (Naphthalene); 98-86-2 (Acetophenone); 103-26-4 (Methyl cinnamate); 103-36-6; 110-83-8 (Cyclohexene); 142-29-0 (Cyclopentene); 498-66-8 (Norbornene); 563-79-1 (2,3-Dimethyl-2-butene); 583-60-8 (2-Methylcyclohexanone); 623-70-1 (Ethyl (E)-Crotonate); 627-27-0 (3-Buten-1-ol); 637-50-3 (1-Propenylbenzene); 763-29-1; 768-56-9 (Allylbenzene); 870-50-8 (Di-tert-butyl azodicarboxylate); 931-88-4 (Cyclooctene); 1118-71-4; 4786-20-3 (2-Butenenitrile); 6117-91-5 (2-Buten-1-ol); 13269-52-8 (trans-3-Hexene) Role: RCT (Reactant), RACT (Reactant or reagent) (manganese-catalyzed hydrohydrazination of alkenes); 493-03-8P; 769-57-3P; 1674-10-8P (1,2-Dimethylcyclohexene); 5402-29-9P (1,2-Dimethylcyclohexanol) Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (manganese-catalyzed hydrohydrazination of alkenes); 180137-93-3P; 345210-67-5P; 704899-91-2P; 704900-21-0P; 704900-28-7P; 704900-42-5P; 704900-46-9P; 704900-48-1P; 704900-57-2P; 773882-00-1P; 773882-02-3P; 773882-03-4P; 773882-04-5P; 773882-05-6P; 773882-06-7P; 773882-07-8P; 773882-08-9P; 773882-09-0P Role: SPN (Synthetic preparation), PREP (Preparation) (manganese-catalyzed hydrohydrazination of alkenes); 789-25-3 (Triphenylsilane); 9004-73-3 (Poly(methylhydrosiloxane); 49718-23-2 Role: RGT (Reagent), RACT (Reactant or reagent) (reductant; manganese-catalyzed hydrohydrazination of alkenes)
21-2
General Organic Chemistry
Laboratorium fuer Organische Chemie,ETH Honggerberg,Zurich,Switz.
Journal
written in English.
704900-51-6P Role: CAT (Catalyst use), SPN (Synthetic preparation), PREP (Preparation), USES (Uses) (cobalt- or manganese-catalyzed hydrohydrazination of alkenes); 62-57-7 (2-Aminoisobutyric acid); 90-02-8 (Salicylaldehyde) Role: RCT (Reactant), RACT (Reactant or reagent) (cobalt- or manganese-catalyzed hydrohydrazination of alkenes); 773882-01-2P Role: BYP (Byproduct), SPN (Synthetic preparation), PREP (Preparation) (manganese-catalyzed hydrohydrazination of alkenes); 14324-99-3P Role: CAT (Catalyst use), SPN (Synthetic preparation), PREP (Preparation), USES (Uses) (manganese-catalyzed hydrohydrazination of alkenes); 67-64-1 (Acetone); 91-20-3 (Naphthalene); 98-86-2 (Acetophenone); 103-26-4 (Methyl cinnamate); 103-36-6; 110-83-8 (Cyclohexene); 142-29-0 (Cyclopentene); 498-66-8 (Norbornene); 563-79-1 (2,3-Dimethyl-2-butene); 583-60-8 (2-Methylcyclohexanone); 623-70-1 (Ethyl (E)-Crotonate); 627-27-0 (3-Buten-1-ol); 637-50-3 (1-Propenylbenzene); 763-29-1; 768-56-9 (Allylbenzene); 870-50-8 (Di-tert-butyl azodicarboxylate); 931-88-4 (Cyclooctene); 1118-71-4; 4786-20-3 (2-Butenenitrile); 6117-91-5 (2-Buten-1-ol); 13269-52-8 (trans-3-Hexene) Role: RCT (Reactant), RACT (Reactant or reagent) (manganese-catalyzed hydrohydrazination of alkenes); 493-03-8P; 769-57-3P; 1674-10-8P (1,2-Dimethylcyclohexene); 5402-29-9P (1,2-Dimethylcyclohexanol) Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (manganese-catalyzed hydrohydrazination of alkenes); 180137-93-3P; 345210-67-5P; 704899-91-2P; 704900-21-0P; 704900-28-7P; 704900-42-5P; 704900-46-9P; 704900-48-1P; 704900-57-2P; 773882-00-1P; 773882-02-3P; 773882-03-4P; 773882-04-5P; 773882-05-6P; 773882-06-7P; 773882-07-8P; 773882-08-9P; 773882-09-0P Role: SPN (Synthetic preparation), PREP (Preparation) (manganese-catalyzed hydrohydrazination of alkenes); 789-25-3 (Triphenylsilane); 9004-73-3 (Poly(methylhydrosiloxane); 49718-23-2 Role: RGT (Reagent), RACT (Reactant or reagent) (reductant; manganese-catalyzed hydrohydrazination of alkenes)
Laboratories
LCSO
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCSO - Laboratory of Catalysis and Organic Synthesis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2007-12-17