000114800 001__ 114800
000114800 005__ 20190213064552.0
000114800 02470 $$2DAR$$a11419
000114800 02470 $$2ISI$$a000250809600011
000114800 0247_ $$2doi$$a10.1021/jp076129d
000114800 037__ $$aARTICLE
000114800 245__ $$aInfluence of the Interaction between Hydrogen Sulfide and Ionic Liquids on Solubility: Experimental and Theoretical Investigation
000114800 269__ $$a2007
000114800 260__ $$c2007
000114800 336__ $$aJournal Articles
000114800 520__ $$aThe soly. of H2S in a series of 1-butyl-3-methylimidazolium ([bmim]+) based ionic liqs. (ILs) with different anions, chloride, tetrafluoroborate ([BF4]-), hexafluorophosphate ([PF6]-), triflate ([TfO]-), and bis(trifluoromethyl)sulfonylimide ([Tf2N]-), and in a series of [Tf2N] ILs with different cations, i.e., N-alkyl-N'-methylimidazolium, 2-methyl-N-methyl-N'-alkyimidazolium, N-alkylpyridinium, N-butyl-N-methylpyrrolidinium, and N-alkyl-N,N-dimethyl-N-(2-hydroxyethyl)ammonium has been detd. using medium-pressure NMR spectroscopy. The obsd. solubilities are significantly higher than those reported for many other gases in ILs, suggesting the occurrence of specific interactions between H2S and the examd. ILs. Quantum chem. calcns. have been used to investigate at a mol. level the interaction between H2S and the [bmim]+-based ILs.
000114800 700__ $$aPomelli, Christian Silvio
000114800 700__ $$aChiappe, Cinzia
000114800 700__ $$0240282$$g157884$$aVidis, Ana
000114800 700__ $$0240013$$g123171$$aLaurenczy, Gabor
000114800 700__ $$0240015$$g149418$$aDyson, Paul J.
000114800 773__ $$j111$$tJOURNAL OF PHYSICAL CHEMISTRY B$$k45$$q13014-13019
000114800 909C0 $$xU9$$0252010$$pLCOM
000114800 909CO $$pSB$$particle$$ooai:infoscience.tind.io:114800
000114800 937__ $$aLCOM-ARTICLE-2007-028
000114800 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000114800 980__ $$aARTICLE