000114746 001__ 114746
000114746 005__ 20190117191533.0
000114746 0247_ $$2doi$$a10.1002/aoc.1317
000114746 037__ $$aARTICLE
000114746 245__ $$aAqueous phase carbon dioxide and bicarbonate hydrogenation catalyzed by cyclopentadienyl ruthenium complexes
000114746 269__ $$a2007
000114746 260__ $$c2007
000114746 336__ $$aJournal Articles
000114746 520__ $$aThe water-sol. ruthenium(II) complexes [Cp'RuX(PTA)2]Y and [CpRuCl(PPh3)(mPTA)]OTf (Cp' = Cp, Cp*, X = Cl and Y = nil; or X = MeCN and Y = PF6; PTA = 1,3,5-triaza-7-phosphaadamantane; mPTA = 1-methyl-1,3,5-triaza-7-phosphaadamantane) were used as catalyst precursors for the hydrogenation of CO2 and bicarbonate in aq. solns., in the absence of amines or other additives, under relatively mild conditions (100 bar H2, 30-80°C), with moderate activities. Kinetic studies showed that the hydrogenation of HCO3– proceeds without an induction period, and that the rate strongly depends on the pH of the reaction medium. High-pressure multinuclear NMR spectroscopy revealed that the ruthenium(II) chloride precursors are quant. converted into the corresponding hydrides under H2 pressure.
000114746 700__ $$aBosquain, Sylvain S.
000114746 700__ $$0240281$$g155779$$aDorcier, Antoine
000114746 700__ $$0240015$$g149418$$aDyson, Paul J.
000114746 700__ $$aErlandsson, Mikael
000114746 700__ $$aGonsalvi, Luca
000114746 700__ $$aLaurenczy, Gabor$$g123171$$0240013
000114746 700__ $$aPeruzzini, Maurizio.
000114746 773__ $$j21$$tAPPLIED ORGANOMETALLIC CHEMISTRY$$k11$$q947-951
000114746 909C0 $$xU9$$0252010$$pLCOM
000114746 909CO $$pSB$$particle$$ooai:infoscience.tind.io:114746
000114746 937__ $$aLCOM-ARTICLE-2007-024
000114746 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000114746 980__ $$aARTICLE