High-pressure effects on the Diels-Alder reaction in room temperature ionic liquids

The effect of pressure on the Diels-Alder reaction was examined in room temperature ionic liquids, followed by high-pressure FT-IR spectroscopy using pressures up to 150&nbsp;MPa. Pressure enhances the kinetic sensitivity of the reaction. The kinetic effect of fluorophobic interactions was examined using ionic liquids with fluorous cations. Ionic liquids in combination with ZnI<SUB>2</SUB> as a Lewis acid catalyst were also studied under high pressure.


Published in:
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 20, 2, 109–114
Year:
2007
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 Record created 2007-03-30, last modified 2018-03-17


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