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research article

Effect of Cs-Incorporated NiOx on the Performance of Perovskite Solar Cells

Kim, Hui-Seon  
•
Seo, Ji-Youn  
•
Xie, Haibing
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2017
Acs Omega

The effect of Cs-incorporated NiOx on perovskite solar cells with an inverted structure was investigated, where NiOx and PCBM were used as selective contacts for holes and electrons, respectively. It was found that the generation of an Ni phase in an NiOx layer was significantly suppressed by employing cesium. Furthermore, Cs-incorporated NiOx enabled holes to be efficiently separated at the interface, showing the improved photoluminescent quenching and thus generating higher short-circuit current. The effect of Cs incorporation was also prominent in the inhibition of recombination. The recombination resistance of Cs-incorporated NiOx was noticeably increased by more than three-fold near the maximum power point, leading to a higher fill factor of 0.78 and consequently a higher power conversion efficiency of 17.2% for the device employing Cs-incorporated NiOx.

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Type
research article
DOI
10.1021/acsomega.7b01179
Web of Science ID

WOS:000418744400059

Author(s)
Kim, Hui-Seon  
Seo, Ji-Youn  
Xie, Haibing
Lira-Cantu, Monica
Zakeeruddin, Shaik M.  
Gratzel, Michael  
Hagfeldt, Anders  
Date Issued

2017

Publisher

Amer Chemical Soc

Published in
Acs Omega
Volume

2

Issue

12

Start page

9074

End page

9079

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
LSPM  
Available on Infoscience
January 15, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/144068
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