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  4. Effect of Steam-to-Carbon Ratio on Degradation of Ni-YSZ Anode Supported Cells
 
research article

Effect of Steam-to-Carbon Ratio on Degradation of Ni-YSZ Anode Supported Cells

Madi, H.
•
Diethelm, S.
•
Van herle, J.
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2013
ECS Transactions

Internal steam reforming (IR) of methane was investigated on Ni- YSZ anode supported cells, looking in particular at the effect of the steam to carbon (S/C) ratio on the degradation rate. The cells were fed with different H2O/CH4 mixtures during 100 hours sequences, alternating with sequences of dry H2 feeding. V-I characterization was performed before and after each sequence, and EIS measurements were performed regularly. A marked degradation was observed during the IR sequences while it was negligible under dry H2 feed. The observed degradation, attributed to carbon deposition on the anode active sites, was partially reversible for S/C >1.5, whereas it became irreversible at lower S/C.

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Type
research article
DOI
10.1149/05701.1517ecst
Author(s)
Madi, H.
Diethelm, S.
Van herle, J.
Petigny, N.
Date Issued

2013

Published in
ECS Transactions
Volume

57

Issue

1

Start page

1517

End page

1525

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SCI-STI-JVH  
Available on Infoscience
February 27, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/145061
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