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  4. Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells
 
research article

Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells

Dualeh, Amalie  
•
Moehl, Thomas  
•
Tetreault, Nicolas  
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2014
Acs Nano

Mesoscopic solid-state solar cells based on the inorganic-organic hybrid perovskite CH(3)NH(3)Pbl(3) in conjunction with the amorphous organic semiconductor spiro-MeOTAD as a hole transport material (HIM) are investigated using impedance spectroscopy (IS). A model to interpret the frequency response of these devices is established by expanding and elaborating on the existing models used for the liquid and solid-state dye-sensitized solar cells. Furthermore, the influence of changing the additive concentrations of tert-butylpyridine and LiTFSI in the HIM and varying the HIM overlayer thickness on top of the sub-micrometer thick TiO2 on the extracted IS parameters is investigated. The internal electrical processes of such devices are studied and correlated with the overall device performance. In particular, the features in the IS responses that are attributed to the ionic and electronic transport properties of the perovskite material and manifest as a slow response at low frequency and an additional RC element at intermediate frequency, respectively, are explored.

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Type
research article
DOI
10.1021/nn404323g
Web of Science ID

WOS:000330542900036

Author(s)
Dualeh, Amalie  
Moehl, Thomas  
Tetreault, Nicolas  
Teuscher, Joel  
Gao, Peng  
Nazeeruddin, Mohammad Khaja  
Graetzel, Michael  
Date Issued

2014

Publisher

American Chemical Society

Published in
Acs Nano
Volume

8

Issue

1

Start page

362

End page

373

Subjects

mesoscopic solar cells

•

perovskite

•

impedance spectroscopy

•

spiro-MeOTAD

•

tert-butylpyridine

•

LiTFSI

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
March 3, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/101320
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