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research article

The Rise of Highly Efficient and Stable Perovskite Solar Cells

Graetzel, Michael  
2017
Accounts Of Chemical Research

Recently, metal halide perovskite solar cells (PSCs) of the general formular ABX(3) where A is a monovalent cation, that is, methylammonium (MA) CH3NH3+center dot, formamidinium CH2(NH2)(2)(+), Cs+, or Rb+, B stands for Pb(II) or Sn(II), and X for iodide or bromide have achieved solar to electric power conversion efficiencies (PCEs) above 22%, exceeding the efficiency of the present market leader polycrystalline silicon while using 1000 times less light harvesting material and simple solution processing for their fabrication. The top performing devices all employ formulations containing a mixture of up to four A cations and iodide as well as a small fraction of bromide as anion, whose emergence will be described in this Commentary. Apart from leading the current PV efficiency race, these new perovskite materials exhibit intense electroluminescence and an extraordinarily high stability under heat and light stress.

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Type
research article
DOI
10.1021/acs.accounts.6b00492
Web of Science ID

WOS:000397478000010

Author(s)
Graetzel, Michael  
Date Issued

2017

Publisher

Amer Chemical Soc

Published in
Accounts Of Chemical Research
Volume

50

Issue

3

Start page

487

End page

491

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
May 1, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/136852
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