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  4. Branched Poly(Aryl Piperidinium) Membranes for Anion-Exchange Membrane Fuel Cells
 
research article

Branched Poly(Aryl Piperidinium) Membranes for Anion-Exchange Membrane Fuel Cells

Wu, Xingyu  
•
Chen, Nanjun
•
Klok, Harm-Anton  
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December 27, 2021
Angewandte Chemie International Edition

Anion-exchange membrane fuel cells (AEMFCs) are a promising, next-generation fuel cell technology. AEMFCs require highly conductive and robust anion-exchange membranes (AEMs), which are challenging to develop due to the tradeoff between conductivity and water uptake. Here we report a method to prepare high-molecular-weight branched poly(aryl piperidinium) AEMs. We show that branching reduces water uptake, leading to improved dimensional stability. The optimized membrane, b-PTP-2.5, exhibits simultaneously high OH- conductivity (>145 mS cm(-1) at 80 degrees C), high mechanical strength and dimensional stability, good processability, and excellent alkaline stability (>1500 h) in 1 M KOH at 80 degrees C. AEMFCs based on b-PTP-2.5 reached peak power densities of 2.3 W cm(-2) in H-2-O-2 and 1.3 W cm(-2) in H-2-air at 80 degrees C. The AEMFCs can run stably under a constant current of 0.2 A cm(-2) over 500 h, during which the b-PTP-2.5 membrane remains stable.

  • Details
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Type
research article
DOI
10.1002/anie.202114892
Web of Science ID

WOS:000734677400001

Author(s)
Wu, Xingyu  
Chen, Nanjun
Klok, Harm-Anton  
Lee, Young Moo
Hu, Xile  
Date Issued

2021-12-27

Publisher

Wiley-VCH Verlag GmbH

Published in
Angewandte Chemie International Edition
Article Number

e202114892

Subjects

Chemistry, Multidisciplinary

•

Chemistry

•

anion exchange membrane

•

branched structure

•

durability

•

fuel cells

•

poly(aryl piperidinium)s

•

hydroxide

•

polymer

•

challenges

•

ionomers

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSCI  
LP  
ISIC-GE  
Available on Infoscience
January 15, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/184491
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