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  4. Dual effect of humidity on cesium lead bromide: enhancement and degradation of perovskite films
 
research article

Dual effect of humidity on cesium lead bromide: enhancement and degradation of perovskite films

Di Girolamo, Diego
•
Dar, M. Ibrahim  
•
Dini, Danilo
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May 21, 2019
Journal of Materials Chemistry A

CsPbBr3 perovskite is highly desired to fabricate many optoelectronic devices: high photovoltage solar cells, tandem solar cells, light-emitting diodes, lasers, photodetectors, field effect transistors etc. However, to realize these applications, resistance to humidity, one of the most important stressing agents, needs to be understood. In this article, we investigate the effect of prolonged exposure (up to 500 h) of CsPbBr3 to approximate to 60% and 80% relative humidity by in situ X-ray diffraction and ex situ scanning electron microscopy, UV-visible spectroscopy and photoluminescence. We show that humidity does not always have detrimental effects. Indeed, the exposure of CsPbBr3 films to humidity for a limited time (2-3 days and 8 minutes for 60% and 80% RH, respectively) enhances their crystallinity. However, prolonged exposure to humidity results in partial degradation of the perovskite phase leading to the concomitant formation of a new, possibly hydrate, crystalline phase. Restoration of 30% RH leads to partial recovery of the initial phase by nucleation of new small CsPbBr3 crystallites. The present findings suggest that post-deposition treatment under controlled humidity might help in producing better films to enhance the efficiency of optoelectronic devices.

  • Details
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Type
research article
DOI
10.1039/c9ta00715f
Web of Science ID

WOS:000472465300065

Author(s)
Di Girolamo, Diego
Dar, M. Ibrahim  
Dini, Danilo
Gontrani, Lorenzo
Caminiti, Ruggero
Mattoni, Alessandro
Graetzel, Michael  
Meloni, Simone  
Date Issued

2019-05-21

Publisher

Royal Society of Chemistry

Published in
Journal of Materials Chemistry A
Volume

7

Issue

19

Start page

12292

End page

12302

Subjects

Chemistry, Physical

•

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Chemistry

•

Energy & Fuels

•

Materials Science

•

light-emitting-diodes

•

halide perovskites

•

solar-cells

•

x-ray

•

molecular-dynamics

•

phase-transitions

•

single-crystals

•

scale synthesis

•

nanocrystals

•

efficiency

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
July 5, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/158885
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