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  4. Investigation Regarding the Role of Chloride in Organic-Inorganic Halide Perovskites Obtained from Chloride Containing Precursors
 
research article

Investigation Regarding the Role of Chloride in Organic-Inorganic Halide Perovskites Obtained from Chloride Containing Precursors

Dar, M. Ibrahim  
•
Arora, Neha  
•
Gao, Peng  
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2014
Nano Letters

As the photovoltaic performance of a device is strongly influenced by the morphology of perovskite, achieving precise control over the crystal formation of organic-inorganic halide perovskites synthesized in the ambience of chloride ions has garnered much attention. Although the resulting morphology dictates the performance of the device considerably, the understanding of the role of chloride ions has been scant. To unravel this mystery, we investigated three different organic-inorganic halide perovskite materials grown from the chloride-containing precursors under different but optimized conditions. Despite the presence of chloride ions in the reaction mixture, scanning transmission electron microscopy- energy dispersive spectroscopy (STEM-EDS) reveals that the CH3NH3PbI3 perovskites formed are chloride-free. Moreover bright field transmission electron microscopy indicates that chloride ions effect the growth of the CH3NH3PbI3.

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Type
research article
DOI
10.1021/nl503279x
Web of Science ID

WOS:000346322800037

Author(s)
Dar, M. Ibrahim  
Arora, Neha  
Gao, Peng  
Ahmad, Shahzada
Graetzel, Michael  
Nazeeruddin, Mohammad Khaja  
Date Issued

2014

Publisher

American Chemical Society

Published in
Nano Letters
Volume

14

Issue

12

Start page

6991

End page

6996

Subjects

Perovskite

•

CH3NH3PbI3

•

Photovoltaic

•

Electron microscopy

•

STEM

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
LPI  
Available on Infoscience
February 20, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/111490
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