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  4. All-inorganic halide perovskites for air-processed "n-i-p" monolithic perovskite/organic hybrid tandem solar cells exceeding 23% efficiency
 
research article

All-inorganic halide perovskites for air-processed "n-i-p" monolithic perovskite/organic hybrid tandem solar cells exceeding 23% efficiency

Mali, Sawanta S.
•
Patil, Jyoti V.
•
Steele, Julian A.
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November 24, 2023
Energy & Environmental Science

All-perovskite tandem solar cells recently surpassed 26% power conversion efficiency using a Sn(ii)-based halide perovskite rear subcell, which introduces several issues related to the chemical instability and the effectiveness of common, inexpensive interconnecting layers. Adopting an all-organic blend as the rear subcell, we report here efficient "n-i-p" monolithic hybrid tandem solar cells based on metal-ion doped all-inorganic gamma-CsPb(I1-xBrx)(3), perovskite front subcells and a solution-processed ternary organic blend rear subcell. Dynamic hot-air deposition of the perovskite films allowed devices to be made and tested entirely in the open air, and passivation of the perovskite layer and the zinc oxide electron selection layer suppressed interfacial recombination and minimized the open-circuit voltage loss (0.025 V). Our devices achieved a maximum efficiency of 23.07% with an open-circuit voltage of 2.110 V, retaining >90% of the initial efficiency over 600 h at maximum power tracking under continuous illumination.

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Type
research article
DOI
10.1039/d3ee02763e
Web of Science ID

WOS:001113916300001

Author(s)
Mali, Sawanta S.
Patil, Jyoti V.
Steele, Julian A.
Nazeeruddin, Mohammad Khaja  
Kim, Jin Hyeok
Hong, Chang Kook
Date Issued

2023-11-24

Publisher

Royal Soc Chemistry

Published in
Energy & Environmental Science
Volume

17

Issue

3

Subjects

Physical Sciences

•

Technology

•

Life Sciences & Biomedicine

•

Photovoltaics

•

Layer

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
FunderGrant Number

National Research Foundation of Korea

2020R1A2C2004880

National Research Foundation of Korea (NRF)

2018R1A6A1A03024334

Priority Research Centers Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology

RS-2023-00248067

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Available on Infoscience
February 20, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/204497
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