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  4. Long-term colloidal stability of 10 carbon nanotube types in the absence/presence of humic acid and calcium
 
research article

Long-term colloidal stability of 10 carbon nanotube types in the absence/presence of humic acid and calcium

Schwyzer, Irene
•
Kaegi, Ralf
•
Sigg, Laura
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2012
Environmental Pollution

The colloidal stabilities of ten carbon nanotubes (CNTs) having varying physico-chemical properties were compared in long-term experiments. The presence of Suwannee River Humic Acid (SRHA) increased the fraction of CNTs in the supernatants (4-88% for the various CNT types) after addition in pre-dispersed form and 20 days of shaking and 5 days of settling. These suspensions were monomodal, containing individually suspended CNTs with highly negative surface charges. Calcium (2 mM) removed most of the CNT types from the supernatant, due to CNT-agglomerate formation initiated by reduction in surface charge. The amount of SRHA adsorbed to the different CNT types did not correlate (r(2) < 0.1) with the percentage of CNTs remaining in suspension. Multiple linear regression analysis revealed that the oxygen content and the diameter of the CNTs significantly influenced the percentage of stabilized CNTs, resulting in an increased fraction of functionalized and large-diameter CNTs that remained in suspension. (c) 2012 Elsevier Ltd. All rights reserved.

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Type
research article
DOI
10.1016/j.envpol.2012.05.004
Web of Science ID

WOS:000307144600009

Author(s)
Schwyzer, Irene
Kaegi, Ralf
Sigg, Laura
Smajda, Rita  
Magrez, Arnaud  
Nowack, Bernd
Date Issued

2012

Publisher

Elsevier Sci Ltd

Published in
Environmental Pollution
Volume

169

Start page

64

End page

73

Subjects

Carbon nanotubes

•

Colloidal stability

•

Agglomeration

•

Calcium

•

Humic acid

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPMC  
Available on Infoscience
February 27, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/89466
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