research article

An investigation of laser intensity and temperature effects in the time-resolved infrared multiphoton dissociation of chlorodifluoromethane

Duperrex, R.
•
Van den Bergh, H.  
1980
Journal of Molecular Structure

The abs. :CF2 concn. is measured in situ and in real time by UV-absorption spectroscopy in the IR multiphoton dissocn. of CF2HCl during and after the laser pulse. The :CF2 prodn. rate is measured as a function of the laser intensity and the temp. at 9.17 mm. This rate increases with the IR intensity and temp. for nearly the whole range of conditions applied. At the highest temps. attained the :CF2 prodn. rates start to decrease with increasing temp.

Type
research article
DOI
10.1016/0022-2860(80)85150-7
Author(s)
Duperrex, R.
Van den Bergh, H.  
Date Issued

1980

Published in
Journal of Molecular Structure
Volume

61

Start page

291

End page

298

Subjects

75-45-6 Role: PROC (Process) (IR multiphoton dissocn. of); 2154-59-8P Role: FORM (Formation

•

nonpreparative)

•

PREP (Preparation) (formation of

•

in IR multiphoton dissocn. of chlorodifluoromethane)

•

IR multiphoton dissocn chlorodifluoromethane; difluorocarbene; fluorocarbene; carbene difluoro

Note

Copyright 2003 ACS

CAPLUS

AN 1980:470686

CAN 93:70686

22-8

Physical Organic Chemistry

Inst. Chim. Phys.,Swiss Fed. Inst. Technol.,Lausanne,Switz. FIELD URL:

Journal

JMOSB4

written in English.

Photolysis (IR laser-induced, of chlorodifluoromethane, multiphoton)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPAS  
Available on Infoscience
February 1, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/63625