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  4. Defect minimization and morphology optimization in TiO2 nanotube thin films, grown on transparent conducting substrate, for dye synthesized solar cell application
 
research article

Defect minimization and morphology optimization in TiO2 nanotube thin films, grown on transparent conducting substrate, for dye synthesized solar cell application

Kuzmych, Oleksandr
•
Nonomura, Kazuteru  
•
Johansson, Erik M. J.
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2012
Thin Solid Films

TiO2 nanotube (TNT) arrays have proven to be a perspective material for dye- or semiconductor sensitized solar cells. Although their prepn. by anodic oxidn. method is well elaborated for Ti foil substrate, the synthesis of high quality, homogeneous TNT arrays on a transparent conductive oxide (TCO) is still assocd. with some exptl. challenges. In this paper a way is presented of prepn. of defect-free, homogeneous TNT film on a TCO substrate by a combination of high temp. Ti sputtering and controlled interrupted anodization in viscous electrolyte. High temp. of the substrate during Ti sputter coating was found crucial for good adhesion between the Ti thin film and TCO, which seems to be the most important condition for synthesis of TNTs from a Ti thin film. The reason of poor adhesion of the Ti layer sputtered at room temp. is discussed in terms of internal stress forces. An Ar-ion sputtering was proposed as a method for removal of the non-organized top porous layer to reveal a well organized tubular geometry of TNTs and control their final lengths. Such control of morphol. of the top layer is important for prepn. of solid state solar cells.

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Type
research article
DOI
10.1016/j.tsf.2012.09.011
Author(s)
Kuzmych, Oleksandr
Nonomura, Kazuteru  
Johansson, Erik M. J.
Nyberg, Tomas
Hagfeldt, Anders  
Skompska, Magdalena
Date Issued

2012

Published in
Thin Solid Films
Volume

522

Start page

71

End page

78

Subjects

dye sensitized solar cell titania nanotube film defect minimization

•

morphol optimization titania nanotube film dye sensitized solar cell

•

titanium sputtering controlled interrupted anodization titania film synthesis

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPM  
Available on Infoscience
July 6, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/115854
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