research article

Allylic Compounds of Magnesium, Lithium and Potassium : sigma- oder pi-Structures ?

Schlosser, Manfred  
•
Staehle, Manfred
1980
Angewandte Chemie International Edition

The s- vs. p-character of title allylmetal compds. was studied via 13C NMR of R2CR1:CRCH2N (R = H, Me2CH, Me3C, R1 = R2 = H; R = R1 = H, R2 = Me; R = H, R1 = R2 = Me; M = Li, K, MgBr) and of deuterated derivs. [on SciFinder (R)]

Type
research article
DOI
10.1002/anie.198004871
Author(s)
Schlosser, Manfred  
Staehle, Manfred
Date Issued

1980

Publisher

Wiley-VCH Verlag GmbH

Published in
Angewandte Chemie International Edition
Volume

19

Start page

487

End page

488

Subjects

Nuclear magnetic resonance (carbon-13

•

in allyllithium

•

-potassium

•

or -magnesium compds.); Conjugation (in allyllithium

•

-potassium

•

or -magnesium compds.); Electron configuration; Molecular structure (of allyllithium

•

-potassium

•

or -magnesium compds.

•

mol structure allylmetal NMR; electron configuration allylmetal NMR; lithium allyl structure NMR; potassium allyl structure NMR; magnesium allyl structure NMR

Note

CAN 93:203793 22-8 Physical Organic Chemistry Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz. Journal 0044-8249 written in German. 1730-25-2; 3052-45-7; 6088-87-5; 7329-38-6; 16327-44-9; 50585-10-9; 63847-45-0; 73891-64-2; 73891-65-3; 73891-66-4; 73891-67-5; 73891-68-6 Role: PRP (Properties) (structure of, carbon-13 NMR and)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSCO  
Available on Infoscience
March 3, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/226795