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  4. Investigation on the dynamics of electron transport and recombination in TiO2 nanotube/nanoparticle composite electrodes for dye-sensitized solar cells
 
research article

Investigation on the dynamics of electron transport and recombination in TiO2 nanotube/nanoparticle composite electrodes for dye-sensitized solar cells

Mohammadpour, Raheleh
•
Iraji Zad, Azam
•
Hagfeldt, Anders  
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2011
Physical Chemistry Chemical Physics

In this work, the fabrication and characterization are reported of dye-sensitized solar cells based on TiO2 nanotube/nanoparticle (NT/NP) composite electrodes. TiO2 nanotubes were prepd. by anodization of Ti foil in an org. electrolyte. The nanotubes were chem. sepd. from the foil, ground and added to a TiO2 nanoparticle paste, from which composite NT/NP electrodes were fabricated. In the composite TiO2 films the nanotubes existed in bundles with a length of a few micrometers. By optimizing the amt. of NT in the paste, dye-sensitized solar cells with an efficiency of 5.6% were obtained, a 10% improvement in comparison to solar cells with pure NP electrodes. By increasing the fraction of NT in the electrode the c.d. increased by 20% (from 11.1-13.3 mA cm-2), but the open circuit voltage decreased from 0.78-0.73 V. Electron transport, lifetime and extn. studies were performed to investigate this behavior. A higher fraction of NT in the paste led to more and deeper traps in the resulting composite electrodes. Nevertheless, faster electron transport under short-circuit conditions was found with increased NT content, but the electron lifetime was not improved. The electron diffusion length calcd. for short-circuit conditions was increased 3-fold in composite electrodes with an optimized NT fraction. The charge collection efficiency was more than 90% over a wide range of light intensities, leading to improved solar cell performance.

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Type
research article
DOI
10.1039/c1cp21517e
Author(s)
Mohammadpour, Raheleh
Iraji Zad, Azam
Hagfeldt, Anders  
Boschloo, Gerrit.
Date Issued

2011

Published in
Physical Chemistry Chemical Physics
Volume

13

Start page

21487

End page

21491

Subjects

dye sensitized solar cell titania nanotube nanoparticle composite electrode

•

electron transport recombination dynamics titania nanotube nanoparticle composite electrode

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPM  
Available on Infoscience
July 6, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/115832
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