Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Comparison of Trap-state Distribution and Carrier Transport in Nanotubular and Nanoparticulate TiO2 Electrodes for Dye-Sensitized Solar Cells
 
research article

Comparison of Trap-state Distribution and Carrier Transport in Nanotubular and Nanoparticulate TiO2 Electrodes for Dye-Sensitized Solar Cells

Mohammadpour, Raheleh
•
Iraji Zad, Azam
•
Hagfeldt, Anders  
Show more
2010
ChemPhysChem

Dye-sensitized solar cells (DSCs) with nanotubular TiO2 electrodes of varying thicknesses are compared to DSCs based on conventional nanoparticulate electrodes. Despite the higher degree of order in one-dimensional nanotubular electrodes, electron transport times and diffusion coeffs., detd. under short-circuit conditions, are comparable to those of nanoparticulate electrodes. The quasi-Fermi level, however, is much lower in the nanotubes, suggesting a lower concn. of conduction band electrons. This provides evidence for a much higher diffusion coeff. for conduction band electrons in nanotubes than in nanoparticulate films. The electron lifetime and the diffusion length are significantly longer in nanotubular TiO2 electrodes than in nanoparticulate films. Nanotubular electrodes have a trap distribution that differs significantly from nanoparticulate electrodes; they possess relatively deeper traps and have a characteristic energy of the exponential distribution that is more than two times that of nanoparticulate electrodes.

  • Details
  • Metrics
Type
research article
DOI
10.1002/cphc.201000125
Author(s)
Mohammadpour, Raheleh
Iraji Zad, Azam
Hagfeldt, Anders  
Boschloo, Gerrit.
Date Issued

2010

Published in
ChemPhysChem
Volume

11

Start page

2140

End page

2145

Subjects

DSC titania nanotubular nanoparticulate electrode carrier transport trap distribution

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPM  
Available on Infoscience
July 6, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/115793
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés