research article
Total stereoselective syntheses of beta-C-manno-pyranosides and of beta-C(1 -> 3)-linked disaccharides
1999
(-)-7-Oxabicyclo[2.2.1]hept-5-en-2-one has been converted to (-)-6-exo-[(tert-butyl)dimethylsilyloxy]-7-endo-benzyloxy-8-oxabicyclo[3 .2.1]oct-3-en-2-one and methyl 3,5-di-O-acetyl-2,6-anhydro-4-O-benzoyl-D- glycero-D-galacto-heptouronate that were condensed with Me2AlSPh into a single aldol which was transformed into a beta-D-ManAp-CH(OAc)(1-->3)-alpha-L-GulAp-CH(SEt)(2) derivative. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.
Type
research article
Author(s)
Gerber, P.
Date Issued
1999
Publisher
Published in
Volume
40
Issue
16
Start page
3165
End page
3168
Note
Univ Lausanne, Chim Sect, BCH, CH-1015 Lausanne, Switzerland.
Editorial or Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
November 9, 2005
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