Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. A cost-device efficiency balanced spiro based hole transport material for perovskite solar cells
 
research article

A cost-device efficiency balanced spiro based hole transport material for perovskite solar cells

Hajikhanmirzaei, Leila
•
Shahroosvand, Hashem
•
Pashaei, Babak
Show more
May 14, 2020
Journal Of Materials Chemistry C

Although spiro-MeOTAD 1 is a superior hole-transporting material (HTM) commonly employed in perovskite solar cells (PSC), its high cost is one of the major issues holding back commercialization, which has not been resolved to-date. In this article we introduce a new HTM comprising a cyclic spiro-backbone appended with four diphenylimidazole substituents, namely spiro-omethoxyimidazole, or spiro-OMeIm 2. When compared to the benchmark 1, introduction of the imidazole functionality into this versatile platform decreases the first oxidation potential from 0.6 V to 0.53 V, which approaches the energy of the HOMO of the perovskite light absorber. Studies on PSC devices fabricated from 2 reveal that the values of the short-circuit current (J(sc)) and open-circuit voltage (V-oc) are very similar to 1 and its power efficiency is 11.64 vs. 14.46% recorded for spiro-OMeTAD under the same conditions. Nevertheless, the commercial cost of synthesizing OMeIm is approximately 80% less than the synthetic precursors to the best spiro-OMeTAD derivatives reported to-date, which makes spiro-OMeIm less expensive to produce and therefore a very attractive HTM for the future development of low-cost PSCs.

  • Details
  • Metrics
Type
research article
DOI
10.1039/d0tc00196a
Web of Science ID

WOS:000535913600024

Author(s)
Hajikhanmirzaei, Leila
Shahroosvand, Hashem
Pashaei, Babak
Delle Monache, Gabriele
Nazeeruddin, Mohammad Khaja  
Pilkington, Melanie
Date Issued

2020-05-14

Publisher

ROYAL SOC CHEMISTRY

Published in
Journal Of Materials Chemistry C
Volume

8

Issue

18

Start page

6221

End page

6227

Subjects

Materials Science, Multidisciplinary

•

Physics, Applied

•

Materials Science

•

Physics

•

methoxy substituents

•

high-performance

•

ometad

•

imidazoles

•

design

•

impact

•

meotad

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
Available on Infoscience
June 11, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/169214
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés