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research article

Tuning electronic correlations in transition metal pnictides: Chemistry beyond the valence count

Razzoli, E.
•
Matt, C. E.
•
Kobayashi, M.
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2015
Physical Review B

The effects of electron-electron correlations on the low-energy electronic structure and their relationship with unconventional superconductivity are central aspects in the research on iron-based pnictide superconductors. Here we use soft x-ray angle-resolved photoemission spectroscopy to study how electronic correlations evolve in different chemically substituted iron pnictides. We find that correlations are intrinsically related to the effective filling of the correlated orbitals, rather than to the filling obtained by valence counting. Combined density functional theory and dynamical mean-field theory calculations capture these effects, reproducing the experimentally observed trend in the correlation strength. The occupation-driven trend in the electronic correlation reported in our paper supports and extends the recently proposed connection between cuprate and pnictide phase diagrams.

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Type
research article
DOI
10.1103/PhysRevB.91.214502
Web of Science ID

WOS:000355565000004

Author(s)
Razzoli, E.
Matt, C. E.
Kobayashi, M.
Wang, X. -P.
Strocov, V. N.
Van Roekeghem, A.
Biermann, S.
Plumb, N. C.
Radovic, M.  
Schmitt, T.
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Date Issued

2015

Publisher

Amer Physical Soc

Published in
Physical Review B
Volume

91

Issue

21

Article Number

214502

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSNS  
Available on Infoscience
September 28, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/119282
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