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research article

A stochastic model for electrode effects

Wüthrich, Rolf
•
Fascio, Valia
•
Bleuler, Hannes  
2004
Electrochimica Acta

The mechanism leading to the onset of the electrode effects is still under discussion in the literature. In this contribution it is proposed that the main mechanism responsible of the electrode effects is the formation of a gas film isolating the electrode. This gas film is formed because of a high population density of bubbles on the electrode surface. A simple model considering the bubble evolution as a stochastic renewal process is presented. By introducing some phenomenological relations, the model allows to evaluate the critical voltage and current density as well as the static current-voltage characteristics leading to the onset of the electrode effects.

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Type
research article
DOI
10.1016/j.electacta.2003.12.060
Author(s)
Wüthrich, Rolf
Fascio, Valia
Bleuler, Hannes  
Date Issued

2004

Published in
Electrochimica Acta
Volume

49

Issue

22-23

Start page

4005

End page

4010

Subjects

Electrode effects

•

Gas-evolving vertical electrodes

•

Stochastic processes

•

Telegraph noise equation

•

Bubble Evolution

•

SACE

•

[SACE]

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSRO  
Available on Infoscience
August 9, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/232777
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