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  4. Rate-Determining Step for Electrochemical Reduction of Carbon Dioxide into Carbon Monoxide at Silver Electrodes
 
research article

Rate-Determining Step for Electrochemical Reduction of Carbon Dioxide into Carbon Monoxide at Silver Electrodes

Boutin, Etienne  
•
Haussener, Sophia  
2024
ACS Catalysis

Silver is one of the most studied electrode materials for the electrochemical reduction of carbon dioxide into carbon monoxide, a product with many industrial applications. There is a growing number of reports in which silver is implemented in gas diffusion electrodes as part of a large-scale device to develop commercially relevant technology. Electrochemical models are expected to guide the design and operation toward cost-efficient devices. Despite decades of investigations, there are still uncertainties in the way this reaction should be modeled due to the absence of scientific consensus regarding the reaction mechanism and the nature of the rate-determining step. We review previously reported studies to draw converging conclusions on the value of the Tafel slope and existing species at the electrode surface. We also list conflicting experimental observations and provide leads to tackling these remaining questions.

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Type
research article
DOI
10.1021/acscatal.4c00192
Author(s)
Boutin, Etienne  
Haussener, Sophia  
Date Issued

2024

Published in
ACS Catalysis
Start page

8437

End page

8445

Subjects

Electrochemistry

•

Carbon Dioxide Reduction

•

Carbon Monoxide

•

Silver

•

Mechanism

•

Rate-Determining Step

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRESE  
FunderGrant Number

H2020

851441

FNS-NCCR

180544

Available on Infoscience
May 28, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/208130
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