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research article

Elevated transition temperature in Ge doped VO2 thin films

Krammer, Anna  
•
Magrez, Arnaud
•
Vitale, Wolfgang A.
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2017
Journal Of Applied Physics

Thermochromic GexV1-xO2+y thin films have been deposited on Si (100) substrates by means of reactive magnetron sputtering. The films were then characterized by Rutherford backscattering spectrometry (RBS), four-point probe electrical resistivity measurements, X-ray diffraction, and atomic force microscopy. From the temperature dependent resistivity measurements, the effect of Ge doping on the semiconductor-to-metal phase transition in vanadium oxide thin films was investigated. The transition temperature was shown to increase significantly upon Ge doping (similar to 95 degrees C), while the hysteresis width and resistivity contrast gradually decreased. The precise Ge concentration and the film thickness have been determined by RBS. The crystallinity of phase-pure VO2 monoclinic films was confirmed by XRD. These findings make the use of vanadium dioxide thin films in solar and electronic device applications-where higher critical temperatures than 68 degrees C of pristine VO2 are needed-a viable and promising solution. Published by AIP Publishing.

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Type
research article
DOI
10.1063/1.4995965
Web of Science ID

WOS:000409414100016

Author(s)
Krammer, Anna  
Magrez, Arnaud
Vitale, Wolfgang A.
Mocny, Piotr
Jeanneret, Patrick
Guibert, Edouard
Whitlow, Harry J.
Ionescu, Adrian M.
Schueler, Andreas  
Date Issued

2017

Published in
Journal Of Applied Physics
Volume

122

Issue

4

Article Number

045304

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LESO-PB  
Available on Infoscience
October 9, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/141079
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