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  4. Speciation of Lanthanide Metal Ion Dopants in Microcrystalline All-Inorganic Halide Perovskite CsPbCl3
 
research article

Speciation of Lanthanide Metal Ion Dopants in Microcrystalline All-Inorganic Halide Perovskite CsPbCl3

Kubicki, Dominik J.
•
Prochowicz, Daniel
•
Hofstetter, Albert  
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March 28, 2024
Journal Of The American Chemical Society

Lanthanides are versatile modulators of optoelectronic properties owing to their narrow optical emission spectra across the visible and near-infrared range. Their use in metal halide perovskites (MHPs) has recently gained prominence, although their fate in these materials has not yet been established at the atomic level. We use cesium-133 solid-state NMR to establish the speciation of all nonradioactive lanthanide ions (La3+, Ce3+, Pr3+, Nd3+, Sm3+, Sm2+, Eu3+, Eu2+, Gd3+, Tb3+, Dy3+, Ho3+, Er3+, Tm3+, Yb3+, Lu3+) in microcrystalline CsPbCl3. Our results show that all lanthanides incorporate into the perovskite structure of CsPbCl3 regardless of their oxidation state (+2, +3).

  • Details
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Type
research article
DOI
10.1021/jacs.3c11427
Web of Science ID

WOS:001194368000001

Author(s)
Kubicki, Dominik J.
Prochowicz, Daniel
Hofstetter, Albert  
Ummadisingu, Amita
Emsley, Lyndon  
Date Issued

2024-03-28

Publisher

Amer Chemical Soc

Published in
Journal Of The American Chemical Society
Volume

146

Issue

14

Start page

9554

End page

9563

Subjects

Physical Sciences

•

Spin-Lattice-Relaxation

•

Nuclear-Magnetic-Resonance

•

Mas Nmr

•

Paramagnetic Centers

•

Optical-Properties

•

Phase Segregation

•

Doping Lanthanide

•

Anion-Exchange

•

C-13 Nmr

•

Nanocrystals

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRM  
FunderGrant Number

UK Research and Innovation

EP/Y01376X/1

Swiss National Science Foundation

200020_212046

National Centre for Research and Development

V4-JAPAN/2/14/PeDET/2022

Available on Infoscience
April 17, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/207322
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