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research article

Volatile two-dimensional electron gas in ultrathin BaTiO3 films

Lutz, Peter
•
Moser, Simon
•
Jovic, Vedran
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September 28, 2018
Physical Review Materials

We investigate the metallic surface state in ultrathin films of BaTiO3 by angle-resolved photoemission spectroscopy. We find Fermi-surface contours derived from the Ti 3d t(2g) conduction band, similar as in SrTiO3 but with broader spectral features due to enhanced quasiparticle scattering. Oxygen vacancies created in the x-ray beam spot allow for reversible in situ doping control up to surface carrier densities as high as 1014 cm(-2), but vacancy migration into the subsurface at T >= 285 K quenches the surface state. Our analysis suggests that the charge state of oxygen vacancies in ultrathin films is predominantly 2+, which limits charge-carrier trapping and the formation of localized defect states.

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Type
research article
DOI
10.1103/PhysRevMaterials.2.094411
Web of Science ID

WOS:000446295400004

Author(s)
Lutz, Peter
Moser, Simon
Jovic, Vedran
Chang, Young Jun
Koch, Roland J.
Ulstrup, Soren
Oh, Ji Seop
Moreschini, Luca  
Fatale, Sara  
Grioni, Marco  
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Date Issued

2018-09-28

Publisher

AMER PHYSICAL SOC

Published in
Physical Review Materials
Volume

2

Issue

9

Article Number

094411

Subjects

Materials Science, Multidisciplinary

•

Materials Science

•

thin-films

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srtio3

•

polarization

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surface

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ferroelectricity

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oxides

•

arpes

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
Available on Infoscience
December 13, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/152577
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