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  4. Electrolysis and Co-Electrolysis Performance of SOE Short Stacks
 
conference paper

Electrolysis and Co-Electrolysis Performance of SOE Short Stacks

Diethelm, S.  
•
Van Herle, J.  
•
Montinaro, D.
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2013
Fuel Cells
10th European SOFC Forum', u'10th European SOFC Forum

In this study, two short SOE stacks (6-cells) were characterized in steam-electrolysis mode. The first was based on Ni-YSZ supported cells with LSCF-based air electrodes. The second included LSC-based air electrodes specifically developed within the SOFC600 project. The stacks were fed with a 90% steam, 10% hydrogen mixture, and characterized between 600 and 700 degrees C. For the LSCF-based stack, an average cell voltage of 1.6V was reached at -1Acm(-2) and 700 degrees C, corresponding to 60% steam conversion. The LSC-based stack showed better performances, with 1.25V at -0.8Acm(-2) and 700 degrees C. Durability tests were performed around the thermoneutral voltage (1.35V) for resp. 2,400 (LSCF) and 1,500h (LSC). The average stack degradation rates were resp. +2.8% (kh)(-1) (LSCF) and +1.9% (kh)(-1) (LSC). Twelve load-cycles were also performed on the LSC-stack with no apparent degradation. In addition, co-electrolysis was performed between 750 and 850 degrees C by feeding the stack with a 60% H2O, 30% CO2, and 10% H-2 mixture. Ninety-five percent conversion was reached and the measured outlet syngas composition was close to that predicted by thermodynamics. Steam electrolysis tests were carried out in the same conditions for comparison. The stack performance in the co-electrolysis mode was slightly lower than in the electrolysis mode.

  • Details
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Type
conference paper
DOI
10.1002/fuce.201200178
Web of Science ID

WOS:000327706700024

Author(s)
Diethelm, S.  
Van Herle, J.  
Montinaro, D.
Bucheli, O.
Date Issued

2013

Publisher

Wiley-V C H Verlag Gmbh

Publisher place

Weinheim

Published in
Fuel Cells
Total of pages

7

Volume

13

Issue

4

Start page

631

End page

637

Subjects

Electrolysis

•

Energy Conversion

•

Fuel Cells

•

Hydrogen Production

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SCI-STI-JVH  
Event name
10th European SOFC Forum', u'10th European SOFC Forum
Available on Infoscience
January 9, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/99393
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