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research article

Gaussian density fluctuations and mode coupling theory for supercooled liquids

Zaccarelli, E.
•
Foffi, G.  
•
Sciortino, F.
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2001
Europhysics Letters - European Physical Society Letters (EPL)

The equations of motion for the density modes of a fluid, derived from Newton's equations, are written as a linear generalized Langevin equation. The constraint imposed by the fluctuation-dissipation theorem is used to derive an exact form for the memory function. The resulting equations, solved under the assumption that the noise, and consequently density fluctuations, of the liquid are Gaussian distributed, are equivalent to the random phase approximation for the static structure factor and to the well-known ideal mode coupling theory (MCT) equations for the dynamics. This finding suggests that MCT is a theory of fluid dynamics that becomes exact in a mean-field limit.

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Type
research article
DOI
10.1209/epl/i2001-00395-x
Author(s)
Zaccarelli, E.
Foffi, G.  
Sciortino, F.
Tartaglia, P.
Dawson, K. A.
Date Issued

2001

Publisher

IOP Publishing - EPL Association

Published in
Europhysics Letters - European Physical Society Letters (EPL)
Volume

55

Start page

157

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
GR-FO  
Available on Infoscience
January 28, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/46286
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