In this paper we perform an optimization of Brillouin optical time-domain analysis (BOTDA) sensors for achieving high resolution over long sensing ranges using distributed Raman amplification. By employing an optimized first-order bi-directional Raman amplification scheme and combining high-power fiber-Raman lasers and Fabry-Pérot lasers with low relative-intensity-noise (RIN), we demonstrate distributed sensing over 120 km of standard single-mode fiber with 2 meter spatial resolution and with a strain/temperature accuracy of 45με/2.1°C respectively.