The advancement to Urban 4.0 requires urban digitization and predictive maintenance of infrastructure to improve efficiency, durability, and quality of life. This study aims to integrate intelligent technologies for the predictive maintenance of photovoltaic panel systems, which serve as essential smart city renewable energy sources. In addition, we employ vision transformers (ViT), a deep learning architecture devoted to evolving image analysis, to detect anomalies in PV systems. The ViT model is pre-trained on ImageNet to exploit a comprehensive set of relevant visual features from the PV images and classify the input PV panel. Furthermore, the developed system was integrated into a web application that allows users to upload PV images, automatically detect anomalies, and provide detailed panel information, such as PV panel type, defect probability, and anomaly status. A comparative study using several convolutional neural network architectures (VGG, ResNet, and AlexNet) and the ViT transformer was conducted. Therefore, the adopted ViT model performs excellently in anomaly detection, where the ViT achieves an AUC of 0.96. Finally, the proposed approach excels at the prompt identification of potential defects detection, reducing maintenance costs, advancing equipment lifetime, and optimizing PV system implementation.