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research article

Charge-discharge kinetics of electric-paint displays

Edwards, M. O. M.
•
Andersson, M.
•
Gruszecki, T.
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2004
Journal of Electroanalytical Chemistry

The charge-discharge kinetics of electrochromic displays, based on porous nanostructured viologen-derivatized TiO2 films, were investigated by std. electrochem. techniques. Various display compns. and geometries were studied. Chronocoulometry data were analyzed in terms of a simple approx. model for the display charging in optical switches. It was found that the charging speed of "std. displays" is limited mainly by the elec. resistance in the transparent conducting substrates and the capacitance due to the electrochem. active porous films. Support for the assumed voltage-dependence of the display resistance and capacitance in the charging model comes from cyclic voltammetry and impedance spectroscopy measurements. Based on observations of rapid current pulses following voltage steps, a modified charging model is suggested. In this model, the display capacitance is decompd. in contributions from the porous films and the transparent conductive substrates.

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Type
research article
DOI
10.1016/j.jelechem.2003.10.006
Author(s)
Edwards, M. O. M.
Andersson, M.
Gruszecki, T.
Pettersson, H.
Thunman, R.
Thuraisingham, G.
Vestling, L.
Hagfeldt, A.  
Date Issued

2004

Published in
Journal of Electroanalytical Chemistry
Volume

565

Start page

175

End page

184

Subjects

charge discharge kinetics electrochromic display viologen derivatized titania film

•

elec paint display dyed titania film charge discharge kinetics

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPM  
Available on Infoscience
July 6, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/115700
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