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review article

Resilience pathways for halide perovskite photovoltaics under temperature cycling

Wu, Luyan
•
Hu, Shuaifeng
•
Yang, Feng
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February 19, 2025
Nature Reviews Materials

Metal-halide perovskite solar cells have achieved power conversion efficiencies comparable to those of silicon photovoltaic (PV) devices, approaching 27% for single-junction devices. The durability of the devices, however, lags far behind their performance. Their practical implementation implies the subjection of the material and devices to temperature cycles of varying intensity, driven by diurnal cycles or geographical characteristics. Thus, it is vital to develop devices that are resilient to temperature cycling. This Perspective analyses the behaviour of perovskite devices under temperature cycling. We discuss the crystallographic structural evolution of the perovskite layer, reactions and/or interactions among stacked layers, PV properties and photocatalysed thermal reactions. We highlight effective strategies for improving stability under temperature cycling, such as enhancing material crystallinity or relieving interlayer thermal stress using buffer layers. Additionally, we outline existing standards and protocols for temperature cycling testing and we propose a unified approach that could facilitate valuable cross-study comparisons among scientific and industrial research laboratories. Finally, we share our outlook on strategies to develop perovskite PV devices with exceptional real-world operating stability.

  • Details
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Type
review article
DOI
10.1038/s41578-025-00781-7
Web of Science ID

WOS:001425272300001

Author(s)
Wu, Luyan

University of Cagliari

Hu, Shuaifeng

University of Oxford

Yang, Feng

Henan Normal University

Li, Guixiang  

École Polytechnique Fédérale de Lausanne

Wang, Junke
Zuo, Weiwei

University of Stuttgart

Jeronimo-Rendon, Jose J.

University of Stuttgart

Turren-Cruz, Silver-Hamill

University of Valencia

Saba, Michele

Helmholtz Association

Saliba, Michael

University of Stuttgart

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Date Issued

2025-02-19

Publisher

NATURE PORTFOLIO

Published in
Nature Reviews Materials
Subjects

SOLAR-CELLS

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THERMAL-STABILITY

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DAMP HEAT

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PERFORMANCE

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EFFICIENT

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DEGRADATION

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BEHAVIOR

•

DESIGN

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PHASE

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HYSTERESIS

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Science & Technology

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Technology

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCOM  
FunderFunding(s)Grant NumberGrant URL

European Research Council (ERC)

804519

European Union (EU)

101075330

Marie Sklodowska Curie Actions Postdoc Fellow (UKRI Guarantee)

EP/Y029216/1

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Available on Infoscience
March 3, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/247330
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