Resilience pathways for halide perovskite photovoltaics under temperature cycling
Metal-halide perovskite solar cells have achieved power conversion efficiencies comparable to those of silicon photovoltaic (PV) devices, approaching 27% for single-junction devices. The durability of the devices, however, lags far behind their performance. Their practical implementation implies the subjection of the material and devices to temperature cycles of varying intensity, driven by diurnal cycles or geographical characteristics. Thus, it is vital to develop devices that are resilient to temperature cycling. This Perspective analyses the behaviour of perovskite devices under temperature cycling. We discuss the crystallographic structural evolution of the perovskite layer, reactions and/or interactions among stacked layers, PV properties and photocatalysed thermal reactions. We highlight effective strategies for improving stability under temperature cycling, such as enhancing material crystallinity or relieving interlayer thermal stress using buffer layers. Additionally, we outline existing standards and protocols for temperature cycling testing and we propose a unified approach that could facilitate valuable cross-study comparisons among scientific and industrial research laboratories. Finally, we share our outlook on strategies to develop perovskite PV devices with exceptional real-world operating stability.
WOS:001425272300001
University of Cagliari
University of Oxford
Henan Normal University
École Polytechnique Fédérale de Lausanne
University of Stuttgart
University of Stuttgart
University of Valencia
Helmholtz Association
University of Stuttgart
2025-02-19
REVIEWED
EPFL
Funder | Funding(s) | Grant Number | Grant URL |
European Research Council (ERC) | 804519 | ||
European Union (EU) | 101075330 | ||
Marie Sklodowska Curie Actions Postdoc Fellow (UKRI Guarantee) | EP/Y029216/1 | ||
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