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  4. Squaraine Dyes for Single-Component Shortwave Infrared-Sensitive Photodiodes and Upconversion Photodetectors
 
research article

Squaraine Dyes for Single-Component Shortwave Infrared-Sensitive Photodiodes and Upconversion Photodetectors

Hu, Wei-Hsu  
•
Nuesch, Frank  
•
Giavazzi, Davide
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December 25, 2023
Advanced Optical Materials

Sensitive detection of shortwave infrared (SWIR) light using organic dyes will be a significant advance toward many applications in industry and research. Furthermore, from a fabrication and optimization view, photogeneration of charges in diodes consisting of a single dye layer will be highly attractive. However, SWIR dyes are scarce and organic photodiodes usually utilize a donor-acceptor materials combination to split excitons into charges. Here, it is demonstrated that single-component layers of several SWIR squaraine dyes operate as efficient photodetectors, with peak external quantum efficiency > 40% beyond 1000 nm and sensitivity out to 1300 nm. Photocurrents show a superlinear dependence on reverse bias. It is shown that this results from a field-assisted exciton dissociation mechanism, and not from field-dependent charge injection or extraction. SWIR photodiodes are combined with organic light-emitting diodes to fabricate upconversion photodetectors - devices that convert SWIR photons directly into visible light. Upconverters are characterized by a low turn-on voltage (1.5 V) and a high luminance contrast (on-off ratio 16 000) and SWIR-to-visible (λ = 575 nm) photon conversion efficiency (1.85%). Upconversion photodetectors emerge as a promising alternative to the current inorganic-based imaging technology.

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Type
research article
DOI
10.1002/adom.202302105
Web of Science ID

WOS:001130249600001

Author(s)
Hu, Wei-Hsu  
Nuesch, Frank  
Giavazzi, Davide
Jafarpour, Mohammad  
Hany, Roland
Bauer, Michael
Date Issued

2023-12-25

Published in
Advanced Optical Materials
Subjects

Technology

•

Physical Sciences

•

Organic Upconversion Device

•

Shortwave Infrared

•

Single-Component Photodetector

•

Squaraine Dye

•

Upconversion Photodetector

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

FunderGrant Number

Swiss National Science Foundation

IZBRZ2_186261

Board of the Swiss Federal Institutes of Technology

SFA-AM SCALAR

Available on Infoscience
February 20, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/204826
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