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research article

Self-Aligned Silica Nanoparticle Rear Reflectors for Single-Junction Si and Perovskite-Si Tandem Solar Cells

Turkay, Deniz  
•
Blondiaux, Nicolas
•
Boccard, Matthieu
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2025
Solar RRL

Infrared light management is crucial to maximize the optical performance of crystalline Si-based single junction and tandem solar cells. For this end, a low refractive index dielectric is typically inserted under the rear metal and an electrical contact is obtained locally through the dielectric. However, the realization of such an architecture can require numerous fabrication steps that are time and resource intensive. Herein, a simple approach is proposed in which commercially available, low-cost SiO2 nanoparticles (NPs) are spin coated as rear reflectors on pyramid-textured Si, leaving the pyramid tips locally exposed for direct contact by an electrode without additional patterning. In Si heterojunction solar cells, complementing a 40 nm-thick indium tin oxide (ITO) layer with the SiO2-NPs yields a gain of 0.3 mA cm−2 in short-circuit current density compared to that obtained with a bare, 100 nm-thick ITO layer. Combined with reduced electrical losses, power conversion efficiency gains of 0.5%abs to 0.3%abs for single junction Si and perovskite-Si tandem cells are demonstrated, respectively. Finally, it is shown that the NPs can also be processed on large areas via blade coating and that the process can be further simplified by a change in the fabrication sequence of the SiO2-NP and ITO layers.

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Type
research article
DOI
10.1002/solr.202400704
Scopus ID

2-s2.0-85214408487

Author(s)
Turkay, Deniz  

École Polytechnique Fédérale de Lausanne

Blondiaux, Nicolas

Centre Suisse d'Electronique et de Microtechnique SA

Boccard, Matthieu

École Polytechnique Fédérale de Lausanne

Artuk, Kerem  

École Polytechnique Fédérale de Lausanne

Jacobs, Daniel Anthony

Centre Suisse d'Electronique et de Microtechnique SA

Gay, Julien

Centre Suisse d'Electronique et de Microtechnique SA

Jeangros, Quentin

Centre Suisse d'Electronique et de Microtechnique SA

Ballif, Christophe  

École Polytechnique Fédérale de Lausanne

Wolff, Christian Michael  

École Polytechnique Fédérale de Lausanne

Date Issued

2025

Published in
Solar RRL
Subjects

nanoparticles

•

perovskites

•

rear reflectors

•

silicon

•

tandems

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

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PV-LAB  
Available on Infoscience
January 25, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/244497
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