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research article

A thermally synergistic photo-electrochemical hydrogen generator operating under concentrated solar irradiation

Tembhurne, Saurabh Yuvraj  
•
Nandjou Dongmeza, Fredy Intelligent  
•
Haussener, Sophia  
April 29, 2019
Nature Energy

Achieving high current densities while maintaining high energy conversion efficiency is one of the main challenges for enhanc-ing the competitiveness of photo-electrochemical devices. We describe a concept that allows this challenge to be overcome by operating under concentrated solar irradiation (up to 474 kW m−2), using thermal integration, mass transport optimization and a close electronic integration between the photoabsorber and electrocatalyst. We quantify the increase in the theoretical maximum efficiencies resulting from thermal integration, and experimentally validate the concept using a III–V-based photoab-sorber and IrRuOx–Pt-based electrocatalysts. We reach current densities higher than 0.88 A cm−2 at calculated solar-to-hydro-gen conversion efficiencies above 15%. Device performance, dynamic response and stability are investigated, demonstrating the ability to produce hydrogen stably under varying conditions for more than two hours. The current density and output power (27 W) achieved provide a pathway for device scalability aimed towards the large-scale deployment of photo-electrochemical hydrogen production.

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Type
research article
DOI
10.1038/s41560-019-0373-7
Author(s)
Tembhurne, Saurabh Yuvraj  
Nandjou Dongmeza, Fredy Intelligent  
Haussener, Sophia  
Date Issued

2019-04-29

Published in
Nature Energy
Volume

4

Start page

399

End page

407

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRESE  
FunderGrant Number

FNS

145936

FNS

155876

Available on Infoscience
April 29, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/156152
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