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  4. Perovskitoid-Templated Formation of a 1D@3D Perovskite Structure toward Highly Efficient and Stable Perovskite Solar Cells
 
research article

Perovskitoid-Templated Formation of a 1D@3D Perovskite Structure toward Highly Efficient and Stable Perovskite Solar Cells

Kong, Tengfei
•
Xie, Haibing
•
Zhang, Yang
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July 26, 2021
Advanced Energy Materials

Longevity is a long-standing concern for organic-inorganic hybrid perovskite solar cells (PSCs). Recently, the use of low dimensional perovskite has been proven to be a promising strategy to improve the stability of PSCs. Herein, it is demonstrated that 1D perovskitoid based on 2-diethylaminoethylchloride cations can act as a template to induce 1D@3D perovskite structure, leading to smoother surface texture, longer charge-carrier lifetime, smaller residual tensile strain, and reduced surface-defect density in the perovskite film. With this strategy, highly efficient and stable 1D@3D PSC with excellent reproducibility, showing a champion power conversion efficiency (PCE) of 22.9% under standard AM 1.5 G one sun illumination is realized. The unencapsulated optimized devices can retain 94.7%, 92.4%, and 90.0% of their initial PCEs for 2100, 2200, and 2200 h under ambient air, 85 degrees C and illumination conditions, respectively.

  • Details
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Type
research article
DOI
10.1002/aenm.202101018
Web of Science ID

WOS:000678855700001

Author(s)
Kong, Tengfei
Xie, Haibing
Zhang, Yang
Song, Jing
Li, Yahong
Lim, Eng Liang
Hagfeldt, Anders  
Bi, Dongqin
Date Issued

2021-07-26

Publisher

WILEY-V C H VERLAG GMBH

Published in
Advanced Energy Materials
Article Number

2101018

Subjects

Chemistry, Physical

•

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Physics, Applied

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Physics, Condensed Matter

•

Chemistry

•

Energy & Fuels

•

Materials Science

•

Physics

•

1d

•

2-diethylaminoethylchloride hydrochloride

•

additives

•

perovskitoids

•

templates

•

environmental stability

•

performance

•

degradation

•

migration

•

improves

•

cations

•

impact

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSPM  
Available on Infoscience
August 14, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/180579
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