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research article

Nanocomposites of carbon nanotubes embedded in a (Ti,Al)N coated film

Marot, L.
•
de los Arcos, T.
•
Bünzli, A.
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2012
Surface and Coatings Technology

Titanium aluminum nitride ((Ti,Al)N) thin films are widely used as hard protective coating materials. Due to their remarkable tensile strength and elastic modulus carbon nanotubes (CNTs) are an ideal candidate as reinforcing components in such coatings. In this work (Ti,Al)N thin film were deposited on steel substrate by reactive magnetron sputtering and CNTs were grown on top by chemical vapor deposition (CVD). A second (Ti,Al)N film covered the CNTs in order to achieve a nanocomposite structure similar to reinforced concrete. The chemical evolution of the substrate, structure, morphology and growth of CNTs were analyzed by X-ray photoelectron spectroscopy and scanning electron microscopy. It was possible to achieve homogeneous dispersion of the CNTs within the matrix by adjusting the CVD time. Mechanical testing of the adherence and nanohardness of the (Ti,Al)N/CNT/(Ti,Al)N composite coating were performed by scratch and nanoindentation tests. The improvement of mechanical properties by CNT integration resulted in an increase of the hardness and of Young's modulus. (C) 2012 Elsevier B.V. All rights reserved.

  • Details
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Type
research article
DOI
10.1016/j.surfcoat.2012.09.053
Web of Science ID

WOS:000312760000029

Author(s)
Marot, L.
de los Arcos, T.
Bünzli, A.
Wäckerlin, C.
Steiner, R.
Oelhafen, P.
Meyer, E.
Mathys, D.
Spätig, P.
Covarel, G.
Date Issued

2012

Published in
Surface and Coatings Technology
Volume

212

Start page

223

End page

228

Subjects

Nanocomposite

•

Carbon nanotubes

•

Thin films

•

XPS

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
CRPP  
SPC  
Available on Infoscience
February 7, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/88660
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