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research article
The crystallization kinetics of polyamide-12
The crystallization kinetics of polyamide-12 has been investigated using a combination of differential scanning calorimetry (DSC) and hot-stage optical microscopy. The DSC data for isothermal crystallization were consistent with a simple two-parameter Avrami model for isothermal crystallization and optical measurements of the spherulite growth rates and nucleation density. On the basis of semiempirical expressions for these quantities, it is shown that with small adjustments the model can also account for DSC data for nonisothermal crystallization, provided that corrections are made for the dynamic heat balance between the sample and the DSC oven.
Type
research article
Web of Science ID
WOS:000168065500002
Authors
Publication date
2001
Published in
Volume
279
Issue
4
Start page
312
End page
322
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
June 26, 2006
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