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research article

Molecular Imprinting with Ruthenium Porphyrin Catalysts

Burri, Estelle  
•
Severin, Kay  
2006
CHIMIA

A ruthenium meso-tetra[4-(vinylbenzoxy)benzyl]porphyrin catalyst with four polymerizable side chains was synthesized in three steps from commercially available starting materials. The polymerizable side chains allowed the incorporation of this complex in highly cross-linked mesoporous co-polymers. A block polymer and a molecularly imprinted polymer were prepared by co-polymerization with ethyleneglycol dimethacrylate using chloroform as the porogen. The imprinted polymer was prepared in the presence of aminodiphenylmethane as a template. Subsequent removal of the template created a substrate pocket next to the catalytically active center. Both polymers displayed a high catalytic activity for the oxidation of alcohols and alkanes with 2,6-dichloropyridine-N-oxide as the oxidant while the homogeneous catalyst was completely inactive. Furthermore, the imprinted polymer displayed a significant increase in activity compared to the block co-polymer.

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Type
research article
DOI
10.2533/000942906777674868
Web of Science ID

WOS:000237317800005

Author(s)
Burri, Estelle  
Severin, Kay  
Date Issued

2006

Published in
CHIMIA
Volume

60

Start page

182

End page

183

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCS  
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/229980
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