Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Integration of thin n-type nc-Si:H layers in the window-multilayer stack of heterojunction solar cells
 
research article

Integration of thin n-type nc-Si:H layers in the window-multilayer stack of heterojunction solar cells

Antognini, Luca  
•
Sthioul, Corentin
•
Dreon, Julie  
Show more
December 1, 2022
Solar Energy Materials And Solar Cells

N-type nanocrystalline silicon (nc-Si:H(n)) layers are good candidates to improve current and transport properties in heterojunction solar cells. In this work, we perform thickness series alongside PH3 doping series to unravel the desirable characteristics of nc-Si:H(n) along its growth direction. While increasing the PH3 flow is necessary to improve the conductivity of the layer, we observe that too high flows lead to an amorphization of the first 10???15 nm of the layers. In consequence, either high crystallinity are reached at intermediate PH3 flow, resulting in high doping at the n/TCO interface but a poorly doped nucleation zone, or the material becomes more amorphous at very high PH3 flow, allowing a higher doping in the nucleation zone but a less efficient screening of the barrier with the TCO due to the lower crystallinity. To overcome this trade-off, we integrate a 2.5 nm a-Si:H(n) layer underneath the nc-Si:H(n) layer. We also report on the impact of higher ITO doping as well as on the beneficial effect of an additional SiOx capping not only to form a double anti-reflective coating (DARC), but also to improve contact properties. We observe that each of those three features can improve passivation and selectivity as well as reduce strongly the front contact resistivity (????????????????????????????????????). Our best results are achieved by using a thin a-Si:H(n)/nc-Si:H(n) stack together with an IZrO/SiOx DARC, enabling front ????????????????????????????????????lower than 15 m?? cm2 and an efficiency of 23.7% on screen-printed 2 ?? 2 cm2 solar cells.

Superscript/Subscript Available

  • Details
  • Metrics
Type
research article
DOI
10.1016/j.solmat.2022.111975
Web of Science ID

WOS:000859683800005

Author(s)
Antognini, Luca  
Sthioul, Corentin
Dreon, Julie  
Paratte, Vincent  
Tuerkay, Deniz
Senaud, Laurie-Lou
Ballif, Christophe  
Boccard, Mathieu  
Date Issued

2022-12-01

Publisher

ELSEVIER

Published in
Solar Energy Materials And Solar Cells
Volume

248

Article Number

111975

Subjects

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Materials Science

•

Physics

•

heterojunction

•

carrier-selective passivating contact

•

thin films

•

nanocrystalline silicon

•

nanocrystalline silicon-oxide

•

microcrystalline silicon

•

contact stack

•

front

•

performance

•

tco

•

losses

•

growth

•

films

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
Available on Infoscience
October 10, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/191313
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés