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research article

Dark excitons and the elusive valley polarization in transition metal dichalcogenides

Baranowski, M
•
Surrente, A
•
Maude, D K
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2017
2D Materials

A rate equation model for the dark and bright excitons kinetics is proposed which explains the wide variation in the observed degree of circular polarization of the PL emission in different TMDs monolayers. Our work suggests that the dark exciton states play an important, and previously unsuspected role in determining the degree of polarization of the PL emission. A dark exciton ground state provides a robust reservoir for valley polarization, which tries to maintain a Boltzmann distribution of the bright exciton states in the same valley via the intra valley bright dark exciton scattering mechanism. The dependence of the degree of circular polarization on the detuning energy of the excitation in MoSe2 suggests that the electron-hole exchange interaction dominates over two LA phonon emission mechanism for inter valley scattering in TMDs.

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Type
research article
DOI
10.1088/2053-1583/aa58a0
Web of Science ID

WOS:000410349400001

Author(s)
Baranowski, M
Surrente, A
Maude, D K
Ballottin, M
Mitioglu, A A
Christianen, P C M
Kung, Y C
Dumcenco, D
Kis, A  
Plochocka, P
Date Issued

2017

Publisher

Iop Publishing Ltd

Published in
2D Materials
Volume

4

Issue

2

Article Number

025016

Subjects

2D semiconductors

•

MoSe2

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LANES  
Available on Infoscience
March 27, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/135802
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