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research article

Stepwise synthesis of heterotrimetallic FeII/PdII/AuI coordination cages

Eren, Noga  
•
Fadaei-Tirani, Farzaneh  
•
Severin, Kay  
2024
Inorganic Chemistry Frontiers

The synthesis of heterotrimetallic molecular cages is reported. The assemblies contain three types of coordination compounds: FeII clathrochelate complexes, AuI3(pyrazolate)3 complexes, and [PdII(pyridine)4]2+ complexes. The cages were obtained in a stepwise fashion. A nanometer-sized metalloligand with three terminal 3-pyridyl donor groups was prepared by connection of three FeII clathrochelate complexes via a central Au3(pyrazolate)3 complex. A related strategy was employed for the synthesis of a ditopic N-donor ligand with two functionalized FeII clathrochelate complexes. Combining the tritopic ligand with Pd(CH3CN)42 resulted in the clean formation of a spherical PdII6FeII24AuI24 coordination cage with a diameter of ∼4.1 nm and a molecular weight of 21 kDa. The ditopic metalloligand was used for the construction of a PdII2FeII8AuI12 cage.

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Type
research article
DOI
10.1039/D4QI00340C
Author(s)
Eren, Noga  
Fadaei-Tirani, Farzaneh  
Severin, Kay  
Date Issued

2024

Published in
Inorganic Chemistry Frontiers
Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCS  
Available on Infoscience
May 2, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/207770
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