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research article

Electric field-tunable ferromagnetism in a van der Waals semiconductor up to room temperature

Fu, Deyi
•
Liu, Jiawei
•
Hou, Fuchen
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November 20, 2025
Nature Communications

Ferromagnetic semiconductors, coupling charge transport and magnetism via electrical means, show great promise for spin-based logic devices. Despite decades of efforts to achieve such co-functionality, maintaining ferromagnetic order at room temperature remains elusive. Here, we address this long-standing challenge by implanting dilute Co atoms into few-layer black phosphorus through atomically-thin boron nitride diffusion barrier. Our Co-doped black phosphorus-based devices exhibit ferromagnetism up to room temperature while preserving its high mobility (~ 1000 cm 2 V - 1 s - 1 ) and semiconducting characteristics. By incorporating ferromagnetic Co-doped black phosphorus into magnetic tunnel junction devices, we demonstrate a large tunnelling magnetoresistance that extends up to room temperature. This study presents a new approach to engineering ferromagnetic ordering in otherwise nonmagnetic materials, thereby expanding the repertoire and applications of magnetic semiconductors envisioned thus far.

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Type
research article
DOI
10.1038/s41467-025-59961-2
Author(s)
Fu, Deyi

National University of Singapore

Liu, Jiawei

National University of Singapore

Hou, Fuchen
Chang, Xiao

National University of Singapore

Qu, Tingyu

National University of Singapore

Félisaz, Johan  

École Polytechnique Fédérale de Lausanne

Krishnaswamy, Gunasheel Kauwtilyaa

National University of Singapore

Grebenchuk, Sergey

National University of Singapore

Jie, Yuang

National University of Singapore

Watanabe, Kenji

National Institute for Materials Science

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Date Issued

2025-11-20

Publisher

Springer Science and Business Media LLC

Published in
Nature Communications
Volume

16

Issue

1

Article Number

10197

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
C3MP  
Available on Infoscience
November 24, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/256223
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