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  4. B-Alkylcatecholborane-Mediated Tandem Radical Conjugated Addition-Aldol Cyclization
 
research article

B-Alkylcatecholborane-Mediated Tandem Radical Conjugated Addition-Aldol Cyclization

Beauseigneur, Alice
•
Ericsson, Cecilia
•
Renaud, Philippe
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2009
Organic Letters

A one-pot procedure involving radical conjugate addition of B-alkylcatecholboranes to enones followed by intramolecular aldol reaction is reported. Application to the stereoselective synthesis of monocyclic and bicyclic products with up to four contiguous stereogenic centers is presented.

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Type
research article
DOI
10.1021/ol9014943
Web of Science ID

WOS:000268796700065

Author(s)
Beauseigneur, Alice
Ericsson, Cecilia
Renaud, Philippe
Schenk, Kurt  
Date Issued

2009

Published in
Organic Letters
Volume

11

Start page

3778

End page

3781

Subjects

N-Enoyloxazolidinones

•

Facile Routes

•

Oxime Ether

•

Cycloreduction

•

Hydroxylation

•

Aldehydes

•

Ketones

•

Esters

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
IPSB  
Available on Infoscience
November 30, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/59934
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